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​​​At a pressure of $1$ atmosphere and temperature of $25^{\circ} \mathrm{C}$, $365 \mu \mathrm{~g} \mathrm{~m}{ }^{-3}$ of a pollutant corresponds to mixing ratio of $139$ parts per billion (ppb). The atomic weights: $\mathrm{C}- 12$, $\mathrm{H}-1, \mathrm{O}-16, \mathrm{~N}-14$ and $\mathrm{S}-32$. Which one of the following options most closely represents the pollutant

  1. $\mathrm{SO}_{2}$
  2. $\mathrm{NO}_{2}$
  3. $\mathrm{O}_{3}$
  4. $\mathrm{CO}$

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